Chemistry of Graphene Derivatives: Synthesis, Applications, and Perspectives

Jiri Sturala, Jan Luxa, Martin Pumera, Zdeněk Sofer

Research output: Contribution to journalReview articlepeer-review

95 Citations (Scopus)


The chemistry of graphene and its derivatives is one of the hottest topics of current material science research. The derivatisation of graphene is based on various approaches, and to date functionalization with halogens, hydrogen, various functional groups containing oxygen, sulfur, nitrogen, phosphorus, boron, and several other elements have been reported. Most of these functionalizations are based on sp3 hybridization of carbon atoms in the graphene skeleton, which means the formation of out-of-plane covalent bonds. Several elements were also reported for substitutional modification of graphene, where the carbon atoms are substituted with atoms like nitrogen, boron, and several others. From tens of functional groups, for only two of them were reported full functionalization of graphene skeleton and formation of its stoichiometric counterparts, fluorographene and hydrogenated graphene. The functionalization of graphene is crucial for most of its applications including energy storage and conversion devices, electronic and optic applications, composites, and many others.

Original languageEnglish
Pages (from-to)5992-6006
Number of pages15
JournalChemistry - A European Journal
Issue number23
Publication statusPublished - 2018 Apr 20

Bibliographical note

Funding Information:
This work was supported by Czech Science Foundation (GACR No. 15-09001S and GACR No. 16–05167S) and by specific university research (MSMT No. 20-SVV/2017). This work was created with the financial support of the Neuron Foundation for science support. This work was supported by the project Advanced Functional Nanorobots (reg. No. CZ.02.1.01/0.0/0.0/15_ 003/0000444 financed by the EFRR).

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry


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