CH Bond cleavage of 8-quinolinecarbaldehyde by σ,η3-allyl rhodium(III) complexes

Chul Ho Jun; Yeong Gweon Lim

doi:10.1016/0040-4039(95)00540-S

CH Bond cleavage of 8-quinolinecarbaldehyde by σ,η³-allyl rhodium(III) complexes

Chul Ho Jun, Yeong Gweon Lim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Formation of σ,η³-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to CH bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted η³-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted η³-allyl rhodium complexes with P(OMe)₃ produce β,γ-unsaturated ketones.

Original language	English
Pages (from-to)	3357-3360
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	19
DOIs	https://doi.org/10.1016/0040-4039(95)00540-S
Publication status	Published - 1995 May 8

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(95)00540-S

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title = "CH Bond cleavage of 8-quinolinecarbaldehyde by σ,η3-allyl rhodium(III) complexes",

abstract = "Formation of σ,η3-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to CH bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted η3-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted η3-allyl rhodium complexes with P(OMe)3 produce β,γ-unsaturated ketones.",

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AU - Jun, Chul Ho

AU - Lim, Yeong Gweon

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Y1 - 1995/5/8

N2 - Formation of σ,η3-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to CH bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted η3-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted η3-allyl rhodium complexes with P(OMe)3 produce β,γ-unsaturated ketones.

AB - Formation of σ,η3-allyl rhodium complexes from vinylcyclopropanes and Rh(I), its application to CH bond cleavage of 8-quinolinecarbaldehyde, and generation of alkyl-substituted η3-allyl rhodium complexes are demonstrated. Ligand-promoted reductive eliminations of alkyl-substituted η3-allyl rhodium complexes with P(OMe)3 produce β,γ-unsaturated ketones.

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ER -

CH Bond cleavage of 8-quinolinecarbaldehyde by σ,η³-allyl rhodium(III) complexes

Abstract

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