Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Chul Ho Jun; Dae Yon Lee; Yeon Hee Kim; Hyuk Lee

doi:10.1021/om010087c

Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Chul Ho Jun, Dae Yon Lee, Yeon Hee Kim, Hyuk Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K₂CO₃ to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

Original language	English
Pages (from-to)	2928-2931
Number of pages	4
Journal	Organometallics
Volume	20
Issue number	13
DOIs	https://doi.org/10.1021/om010087c
Publication status	Published - 2001 Jun 25

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om010087c

Cite this

@article{da3968a66ceb4331accb60a02b9e6edd,

title = "Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex",

abstract = "Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.",

author = "Jun, {Chul Ho} and Lee, {Dae Yon} and Kim, {Yeon Hee} and Hyuk Lee",

year = "2001",

month = jun,

day = "25",

doi = "10.1021/om010087c",

language = "English",

volume = "20",

pages = "2928--2931",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

AU - Jun, Chul Ho

AU - Lee, Dae Yon

AU - Kim, Yeon Hee

AU - Lee, Hyuk

PY - 2001/6/25

Y1 - 2001/6/25

N2 - Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

AB - Various unstrained sec-alcohols, including cycloalkanols, reacted with alkenes under a catalytic system of Rh(I) complex, 2-amino-3-picoline, and K2CO3 to give the alkyl-group-exchanged ketones through transfer hydrogenation and consecutive carbon-carbon bond activation. The presence of base is essential to enhance the rate of the oxidation step, and alkene acts as a hydrogen acceptor and a substrate of the carbon-carbon coupling reaction.

UR - http://www.scopus.com/inward/record.url?scp=0035948514&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035948514&partnerID=8YFLogxK

U2 - 10.1021/om010087c

DO - 10.1021/om010087c

M3 - Article

AN - SCOPUS:0035948514

SN - 0276-7333

VL - 20

SP - 2928

EP - 2931

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this