Catalytic activities of new arsine-dihydrido ruthenium(II) complexes in the homogeneous hydrogenation of aldehyde

Je Yun Kim; Moo Jin Jun; Won Yong Lee

doi:10.1016/0277-5387(96)00108-8

Catalytic activities of new arsine-dihydrido ruthenium(II) complexes in the homogeneous hydrogenation of aldehyde

Je Yun Kim, Moo Jin Jun, Won Yong Lee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A series of new arsine-dihydrido ruthenium(II) complexes, [RuH₂(CO) (AsPh₃)₃] (1) and [RuH₂(CO)(AsPh₃)(L-L)], [L-L = diars (2), arphos (3), diphos (4)], has been synthesized and characterized by IR, ¹H NMR and elemental analysis. The catalytic activities of these complexes for the hydrogenation of propionaldehyde to yield propan-1-ol have been examined at 130°C and 30 atm hydrogen pressure, and compared with the catalytic activity of the well-known complex, [RuH₂(CO)(PPh₃)₃] (5). [RuH₂(CO) (AsPh₃)₃] showed lower catalytic activity than that of [RuH₂(CO) (PPh₃)₃]. Complexes having a chelate ring have shown higher catalytic activities than that of [RuH₂(CO)(AsPh₃)₃]. Overall, the catalytic activities were found to decrease in the order 4 > 3 > 2 > 5 > 1.

Original language	English
Pages (from-to)	3787-3793
Number of pages	7
Journal	Polyhedron
Volume	15
Issue number	21
DOIs	https://doi.org/10.1016/0277-5387(96)00108-8
Publication status	Published - 1996 Aug 5

Bibliographical note

Funding Information:
late ring will have higher catalytic activities than the compounds having the weaker bond forming arsenic donor atom in the chelate ring. The experimental results show good agreement with the present results and also our previous reports.3 AcknoM;ledgements-Financial support from the Basic Science Research Institute, Ministry of Education of Republic of Korea (Grant No. BSRI-94-3426) is gratefully acknowledged.

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0277-5387(96)00108-8

Cite this

@article{899bf31804024f07b737fa1fcb5e0572,

title = "Catalytic activities of new arsine-dihydrido ruthenium(II) complexes in the homogeneous hydrogenation of aldehyde",

abstract = "A series of new arsine-dihydrido ruthenium(II) complexes, [RuH2(CO) (AsPh3)3] (1) and [RuH2(CO)(AsPh3)(L-L)], [L-L = diars (2), arphos (3), diphos (4)], has been synthesized and characterized by IR, 1H NMR and elemental analysis. The catalytic activities of these complexes for the hydrogenation of propionaldehyde to yield propan-1-ol have been examined at 130°C and 30 atm hydrogen pressure, and compared with the catalytic activity of the well-known complex, [RuH2(CO)(PPh3)3] (5). [RuH2(CO) (AsPh3)3] showed lower catalytic activity than that of [RuH2(CO) (PPh3)3]. Complexes having a chelate ring have shown higher catalytic activities than that of [RuH2(CO)(AsPh3)3]. Overall, the catalytic activities were found to decrease in the order 4 > 3 > 2 > 5 > 1.",

author = "Kim, {Je Yun} and Jun, {Moo Jin} and Lee, {Won Yong}",

note = "Funding Information: late ring will have higher catalytic activities than the compounds having the weaker bond forming arsenic donor atom in the chelate ring. The experimental results show good agreement with the present results and also our previous reports.3 AcknoM;ledgements-Financial support from the Basic Science Research Institute, Ministry of Education of Republic of Korea (Grant No. BSRI-94-3426) is gratefully acknowledged.",

year = "1996",

month = aug,

day = "5",

doi = "10.1016/0277-5387(96)00108-8",

language = "English",

volume = "15",

pages = "3787--3793",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "21",

}

TY - JOUR

T1 - Catalytic activities of new arsine-dihydrido ruthenium(II) complexes in the homogeneous hydrogenation of aldehyde

AU - Kim, Je Yun

AU - Jun, Moo Jin

AU - Lee, Won Yong

N1 - Funding Information: late ring will have higher catalytic activities than the compounds having the weaker bond forming arsenic donor atom in the chelate ring. The experimental results show good agreement with the present results and also our previous reports.3 AcknoM;ledgements-Financial support from the Basic Science Research Institute, Ministry of Education of Republic of Korea (Grant No. BSRI-94-3426) is gratefully acknowledged.

PY - 1996/8/5

Y1 - 1996/8/5

N2 - A series of new arsine-dihydrido ruthenium(II) complexes, [RuH2(CO) (AsPh3)3] (1) and [RuH2(CO)(AsPh3)(L-L)], [L-L = diars (2), arphos (3), diphos (4)], has been synthesized and characterized by IR, 1H NMR and elemental analysis. The catalytic activities of these complexes for the hydrogenation of propionaldehyde to yield propan-1-ol have been examined at 130°C and 30 atm hydrogen pressure, and compared with the catalytic activity of the well-known complex, [RuH2(CO)(PPh3)3] (5). [RuH2(CO) (AsPh3)3] showed lower catalytic activity than that of [RuH2(CO) (PPh3)3]. Complexes having a chelate ring have shown higher catalytic activities than that of [RuH2(CO)(AsPh3)3]. Overall, the catalytic activities were found to decrease in the order 4 > 3 > 2 > 5 > 1.

AB - A series of new arsine-dihydrido ruthenium(II) complexes, [RuH2(CO) (AsPh3)3] (1) and [RuH2(CO)(AsPh3)(L-L)], [L-L = diars (2), arphos (3), diphos (4)], has been synthesized and characterized by IR, 1H NMR and elemental analysis. The catalytic activities of these complexes for the hydrogenation of propionaldehyde to yield propan-1-ol have been examined at 130°C and 30 atm hydrogen pressure, and compared with the catalytic activity of the well-known complex, [RuH2(CO)(PPh3)3] (5). [RuH2(CO) (AsPh3)3] showed lower catalytic activity than that of [RuH2(CO) (PPh3)3]. Complexes having a chelate ring have shown higher catalytic activities than that of [RuH2(CO)(AsPh3)3]. Overall, the catalytic activities were found to decrease in the order 4 > 3 > 2 > 5 > 1.

UR - http://www.scopus.com/inward/record.url?scp=0000624067&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000624067&partnerID=8YFLogxK

U2 - 10.1016/0277-5387(96)00108-8

DO - 10.1016/0277-5387(96)00108-8

M3 - Article

AN - SCOPUS:0000624067

SN - 0277-5387

VL - 15

SP - 3787

EP - 3793

JO - Polyhedron

JF - Polyhedron

IS - 21

ER -

Catalytic activities of new arsine-dihydrido ruthenium(II) complexes in the homogeneous hydrogenation of aldehyde

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this