Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane

Youn Sang Bae; Omar K. Farha; Alexander M. Spokoyny; Chad A. Mirkin; Joseph T. Hupp; Randall Q. Snurr

doi:10.1039/b805785k

Carborane-based metal-organic frameworks as highly selective sorbents for CO₂ over methane

Youn Sang Bae, Omar K. Farha, Alexander M. Spokoyny, Chad A. Mirkin, Joseph T. Hupp, Randall Q. Snurr

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

333 Citations (Scopus)

Abstract

Separation of CO₂/CH₄ mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO₂ over CH₄ (∼17) are obtained, especially in the material with open metal sites.

Original language	English
Pages (from-to)	4135-4137
Number of pages	3
Journal	Chemical Communications
Issue number	35
DOIs	https://doi.org/10.1039/b805785k
Publication status	Published - 2008

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Cite this

@article{4810626599a6438c85ca585360081d70,

title = "Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane",

abstract = "Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.",

author = "Bae, {Youn Sang} and Farha, {Omar K.} and Spokoyny, {Alexander M.} and Mirkin, {Chad A.} and Hupp, {Joseph T.} and Snurr, {Randall Q.}",

year = "2008",

doi = "10.1039/b805785k",

language = "English",

pages = "4135--4137",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "35",

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AU - Bae, Youn Sang

AU - Farha, Omar K.

AU - Spokoyny, Alexander M.

AU - Mirkin, Chad A.

AU - Hupp, Joseph T.

AU - Snurr, Randall Q.

PY - 2008

Y1 - 2008

N2 - Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

AB - Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

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DO - 10.1039/b805785k

M3 - Article

C2 - 18802507

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SP - 4135

EP - 4137

JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Carborane-based metal-organic frameworks as highly selective sorbents for CO₂ over methane

Abstract

All Science Journal Classification (ASJC) codes

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