Calculations of the rotational lines and their strength for the swan band of C2 molecules: A study on the degenerate four wave mixing spectrum

Jae Seok Ryu, Jae Won Hahn

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1 Citation (Scopus)

Abstract

Molecular constants of (0, 0) and (1, 0) bands of C2 are obtained for the Hamiltonian formalism proposed by Zare et al. [J. Mol. Spectrosc. 46 (1973) 37]. Both a conversion method from molecular constants of Brown's Hamiltonian formalism and a nonlinear least-square-fit method are applied. The calculated rotational lines match the results of experiment within the range of 0.06-0.001 cm-1. Using these molecular constants, the spectrum of degenerate four wave mixing for (0, 0) and (1, 0) bands of C2 is calculated at 3000 K for a line-shape function of a Lorentzian cubed profile.

Original languageEnglish
Pages (from-to)6217-6222
Number of pages6
JournalJapanese Journal of Applied Physics
Volume37
Issue number11
DOIs
Publication statusPublished - 1998 Nov

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

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