Anodic TiO2 nanotube layer directly formed on the inner surface of Ti pipe for a tubular photocatalytic reactor

Hyoung Il Kim, Doohun Kim, Wooyul Kim, Yoon Cheol Ha, Seong Ju Sim, Sujeong Kim, Wonyong Choi

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12 Citations (Scopus)


We demonstrated the successful water treatment performance of a continuous-flow tubular TiO2 nanotube reactor made of Ti pipe where a TiO2 nanotube (TNT) layer was directly formed on the inner wall by an electrochemical anodization process. A cylindrical UV lamp was inserted into the pipe to irradiate the inner TNT surface as a light source. To optimize the thickness of TNT layer on Ti pipe, TNT layers with 1, 5 and 10 μm thickness were prepared and their photocatalytic activities were tested for the degradation of various organic substrates (acid orange 7 (AO7), dichloroacetate (DCA), and 4-chlorophenol (4-CP)) under UV illumination. The TNT layer with 10 μm thickness showed the highest photocatalytic activity, with first-order removal rate constants (k:min-1) of 0.019, 0.039, and 0.025 for AO7, 4-CP, and DCA, respectively. The directly formed TNTs (10 μm thickness) on Ti pipes in the continuous-flow tubular TNT reactor, having a strong adhesiveness and a high surface area, enabled the successful degradation of organic compounds and to have kept the activity without decrease during the repeated cycles and long-term experiments. The photocatalytic performance of the tubular TNT reactor was tested with a higher concentration, smaller volume ([4-CP]0 = 100 μM, solution vol. = 15 mL) and a lower concentration, larger volume ([4-CP]0 = 20 μM, solution vol. = 100 mL) in the circulation-flow mode (20 mL min-1). A good performance was achieved under the low intensity UV illumination (≈2 mW cm-2) with a half-life of ca. 50 min and ca. 11 h with 80% and 79% removal of TOC for the above two test conditions, respectively. The proposed tubular TNT reactor can be an effective option in the design of continuous flow-type photocatalytic reactors for practical water purification.

Original languageEnglish
Pages (from-to)174-181
Number of pages8
JournalApplied Catalysis A: General
Publication statusPublished - 2016 Jul 5

Bibliographical note

Funding Information:
This research was financially supported by the Global Research Laboratory (GRL) Program (No. NRF-2014K1A1A2041044), which was funded by the Korea Government (MSIP) through the National Research Foundation (NRF) .

Publisher Copyright:
© 2015 Elsevier B.V.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Process Chemistry and Technology


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