Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

Philjae Kang; Sooyong Jung; Junhyung Lee; Hye Ji Kang; Hyehee Lee; Moon Gun Choi

doi:10.1039/c6dt01834c

Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

Philjae Kang, Sooyong Jung, Junhyung Lee, Hye Ji Kang, Hyehee Lee, Moon Gun Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF₃SO₃ and AgClO₄ afforded the 1D linear polymer [Ag(dmotz)(CF₃SO₃)]_n (1) and the 2D grid polymer {[Ag(dmotz)₂](ClO₄)}_n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO₄]^- and dmotz; even on using excess [CF₃SO₃]^-, conversion from 2 to 1 was not observed.

Original language	English
Pages (from-to)	11949-11952
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	30
DOIs	https://doi.org/10.1039/c6dt01834c
Publication status	Published - 2016

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© The Royal Society of Chemistry 2016.

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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title = "Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions",

abstract = "Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF3SO3 and AgClO4 afforded the 1D linear polymer [Ag(dmotz)(CF3SO3)]n (1) and the 2D grid polymer {[Ag(dmotz)2](ClO4)}n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO4]- and dmotz; even on using excess [CF3SO3]-, conversion from 2 to 1 was not observed.",

author = "Philjae Kang and Sooyong Jung and Junhyung Lee and Kang, {Hye Ji} and Hyehee Lee and Choi, {Moon Gun}",

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doi = "10.1039/c6dt01834c",

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T1 - Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

AU - Kang, Philjae

AU - Jung, Sooyong

AU - Lee, Junhyung

AU - Kang, Hye Ji

AU - Lee, Hyehee

AU - Choi, Moon Gun

PY - 2016

Y1 - 2016

N2 - Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF3SO3 and AgClO4 afforded the 1D linear polymer [Ag(dmotz)(CF3SO3)]n (1) and the 2D grid polymer {[Ag(dmotz)2](ClO4)}n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO4]- and dmotz; even on using excess [CF3SO3]-, conversion from 2 to 1 was not observed.

AB - Mechanochemical reactions of 3,6-dimethoxy-s-tetrazine (dmotz) with AgCF3SO3 and AgClO4 afforded the 1D linear polymer [Ag(dmotz)(CF3SO3)]n (1) and the 2D grid polymer {[Ag(dmotz)2](ClO4)}n (2), respectively. Mechanochemical processes convert 1 to 2 in the presence of an equivalent of [ClO4]- and dmotz; even on using excess [CF3SO3]-, conversion from 2 to 1 was not observed.

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Anion induced structural transformation in silver-(3,6-dimethoxy-1,2,4,5-tetrazine) coordination polymers under mechanochemical conditions

Abstract

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