Amphiphilic Graft Copolymer Nanospheres: From Colloidal Self-Assembly to CO2 Capture Membranes

Harim Jeon, Dong Jun Kim, Min Su Park, Du Yeol Ryu, Jong Hak Kim

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)


Colloidal nanosphere self-assembly effectively generates ordered nanostructures, prompting tremendous interest in many applications such as photonic crystals and templates for inverse opal fabrication. Here we report the self-assembly of low-cost, graft copolymer nanospheres for CO2 capture membranes. Specifically, poly(dimethylsiloxane)-graft-poly(4-vinylpyridine) (PDMS-g-P4VP) is synthesized via one-pot, free radical dispersion polymerization to give discrete monodisperse nanospheres. These nanospheres comprise a surface-anchored highly permeable PDMS layer and internal CO2-philic P4VP spherical core. Their diameter is controllable below the submicrometer range by varying grafting ratios. The colloidal dispersion forms a long-range, close-packed hexagonal array on a substrate by inclined deposition and convective assembly. The array shows dispersion medium-dependent packing characteristics. A thermodynamic correlation is determined using different solvents to obtain stable PDMS-g-P4VP dispersions and interpreted in terms of Flory-Huggins interaction parameter. As a proof-of-concept, the implementation of these nanospheres into membranes simultaneously enhances the CO2 permeability and CO2/N2 selectivity of PDMS-based transport matrixes. Upon physical aging of the solution, the CO2/N2 selectivity is improved up to 26, one of the highest values for highly permeable PDMS-based polymeric membranes.

Original languageEnglish
Pages (from-to)9454-9461
Number of pages8
JournalACS Applied Materials and Interfaces
Issue number14
Publication statusPublished - 2016 Apr 27

Bibliographical note

Funding Information:
This study was supported by the Korea Center for Artificial Photosynthesis (KCAP) (Grant 2009-0093883) funded by the National Research Foundation (NRF), the Human Resources Program in Energy Technology (Grant 20154010200810), and the Energy Efficiency & Resources (Grant 20122010100040) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP).

Publisher Copyright:
© 2016 American Chemical Society.

All Science Journal Classification (ASJC) codes

  • Materials Science(all)


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