Altering the binding affinities of tetraruthenocycles for polycyclic aromatic hydrocarbons by post-assembly modification

Younghun Kim; Philjae Kang; Han Sol Oh; Hyeon Mo Cho; Moon Gun Choi

doi:10.1039/d2cc01544g

Altering the binding affinities of tetraruthenocycles for polycyclic aromatic hydrocarbons by post-assembly modification

Younghun Kim, Philjae Kang, Han Sol Oh, Hyeon Mo Cho, Moon Gun Choi

Research output: Contribution to journal › Article › peer-review

Abstract

We developed a strategy for manipulating the binding strength of polycyclic aromatic hydrocarbons (PAHs) via covalent post-assembly modification (PAM) of tetranuclear ruthenium macrocycles containing s-tetrazine ligands. The macrocycles act as efficient receptors for various PAHs. Inverse electron demand Diels-Alder (IEDDA) reaction of the macrocycles was applied to reduce the binding ability significantly.

Original language	English
Pages (from-to)	6304-6307
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	43
DOIs	https://doi.org/10.1039/d2cc01544g
Publication status	Published - 2022 Apr 29

Bibliographical note

Publisher Copyright:
© 2022 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d2cc01544g

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abstract = "We developed a strategy for manipulating the binding strength of polycyclic aromatic hydrocarbons (PAHs) via covalent post-assembly modification (PAM) of tetranuclear ruthenium macrocycles containing s-tetrazine ligands. The macrocycles act as efficient receptors for various PAHs. Inverse electron demand Diels-Alder (IEDDA) reaction of the macrocycles was applied to reduce the binding ability significantly.",

author = "Younghun Kim and Philjae Kang and Oh, {Han Sol} and Cho, {Hyeon Mo} and Choi, {Moon Gun}",

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AU - Choi, Moon Gun

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AB - We developed a strategy for manipulating the binding strength of polycyclic aromatic hydrocarbons (PAHs) via covalent post-assembly modification (PAM) of tetranuclear ruthenium macrocycles containing s-tetrazine ligands. The macrocycles act as efficient receptors for various PAHs. Inverse electron demand Diels-Alder (IEDDA) reaction of the macrocycles was applied to reduce the binding ability significantly.

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Altering the binding affinities of tetraruthenocycles for polycyclic aromatic hydrocarbons by post-assembly modification

Abstract

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