A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation

Dae Yon Lee; Boo Sun Hong; Eung Goo Cho; Hyuk Lee; Chul Ho Jun

doi:10.1021/ja034337n

A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation

Dae Yon Lee, Boo Sun Hong, Eung Goo Cho, Hyuk Lee, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

The carbon-carbon triple bond in alkyne is cleaved via hydroacylation followed by retro-Mannich type fragmentation in the presence of aldehyde, which triggers a successive C-C bond cleavage.

Original language	English
Pages (from-to)	6372-6373
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	21
DOIs	https://doi.org/10.1021/ja034337n
Publication status	Published - 2003 May 28

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja034337n

Cite this

@article{fb10e11db1de4175a9554d82646bf06c,

title = "A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation",

abstract = "The carbon-carbon triple bond in alkyne is cleaved via hydroacylation followed by retro-Mannich type fragmentation in the presence of aldehyde, which triggers a successive C-C bond cleavage.",

author = "Lee, {Dae Yon} and Hong, {Boo Sun} and Cho, {Eung Goo} and Hyuk Lee and Jun, {Chul Ho}",

year = "2003",

month = may,

day = "28",

doi = "10.1021/ja034337n",

language = "English",

volume = "125",

pages = "6372--6373",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation

AU - Lee, Dae Yon

AU - Hong, Boo Sun

AU - Cho, Eung Goo

AU - Lee, Hyuk

AU - Jun, Chul Ho

PY - 2003/5/28

Y1 - 2003/5/28

N2 - The carbon-carbon triple bond in alkyne is cleaved via hydroacylation followed by retro-Mannich type fragmentation in the presence of aldehyde, which triggers a successive C-C bond cleavage.

AB - The carbon-carbon triple bond in alkyne is cleaved via hydroacylation followed by retro-Mannich type fragmentation in the presence of aldehyde, which triggers a successive C-C bond cleavage.

UR - http://www.scopus.com/inward/record.url?scp=0037837714&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037837714&partnerID=8YFLogxK

U2 - 10.1021/ja034337n

DO - 10.1021/ja034337n

M3 - Article

C2 - 12785769

AN - SCOPUS:0037837714

SN - 0002-7863

VL - 125

SP - 6372

EP - 6373

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 21

ER -

A hydroacylation-triggered carbon-carbon triple bond cleavage in alkynes via retro-Mannich type fragmentation

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this