A highly active catalyst system for intermolecular hydroacylation

Chul Ho Jun; Dae Yon Lee; Hyuk Lee; Jun Bae Hong

doi:10.1002/1521-3773(20000901)39:17<3070::AID-ANIE3070>3.0.CO;2-G

A highly active catalyst system for intermolecular hydroacylation

Chul Ho Jun, Dae Yon Lee, Hyuk Lee, Jun Bae Hong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

157 Citations (Scopus)

Abstract

Adding benzoic acid and aniline as cocatalysts to the Rh 1/2 -amino-3-picoline catalyzed hydroacylation of alkenes with aldehydes to give ketones results in a remarkable improvement in yield and activity [for example, Eq. (1)]. This is one of the few examples of a successful intermolecular hydroacylation reaction.

Original language	English
Pages (from-to)	3070-3072
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20000901)39:17<3070::AID-ANIE3070>3.0.CO;2-G
Publication status	Published - 2000 Sept 1

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/1521-3773(20000901)39:17<3070::AID-ANIE3070>3.0.CO;2-G

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AB - Adding benzoic acid and aniline as cocatalysts to the Rh 1/2 -amino-3-picoline catalyzed hydroacylation of alkenes with aldehydes to give ketones results in a remarkable improvement in yield and activity [for example, Eq. (1)]. This is one of the few examples of a successful intermolecular hydroacylation reaction.

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A highly active catalyst system for intermolecular hydroacylation

Abstract

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