A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds

Leo A. Paquette; Tae Jinsung

doi:10.1016/S0040-4039(99)01167-3

A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds

Leo A. Paquette, Tae Jinsung

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.

Original language	English
Pages (from-to)	5971-5974
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	33
DOIs	https://doi.org/10.1016/S0040-4039(99)01167-3
Publication status	Published - 1999 Aug 13

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(99)01167-3

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title = "A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds",

abstract = "The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.",

author = "Paquette, {Leo A.} and Tae Jinsung",

year = "1999",

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AU - Jinsung, Tae

PY - 1999/8/13

Y1 - 1999/8/13

N2 - The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.

AB - The stereochemical course of the hydride reduction and of the 1,2- addition of allylmagnesium bromide as well as the Normant reagent to 1 has been determined.

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U2 - 10.1016/S0040-4039(99)01167-3

DO - 10.1016/S0040-4039(99)01167-3

M3 - Article

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 33

ER -

A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds

Abstract

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