A convenient method for the synthesis of alkenes from vic-diols via cyclic sulfates with magnesium iodide

Doo Ok Jang; Yung Hyup Joo

doi:10.1080/00032719808006486

A convenient method for the synthesis of alkenes from vic-diols via cyclic sulfates with magnesium iodide

Doo Ok Jang, Yung Hyup Joo

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reaction of cyclic sulfates of vic-diols with magnesium iodide in acetonitrile produced the corresponding olefins in excellent isolated yields at room temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave it mixture of cis- and trans- alkenes. However, the cyclic sulfate of cyclic cis-diol afforded the corresponding cis-alkene only.

Original language	English
Pages (from-to)	871-877
Number of pages	7
Journal	Synthetic Communications
Volume	28
Issue number	5
DOIs	https://doi.org/10.1080/00032719808006486
Publication status	Published - 1998

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1080/00032719808006486

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title = "A convenient method for the synthesis of alkenes from vic-diols via cyclic sulfates with magnesium iodide",

abstract = "Reaction of cyclic sulfates of vic-diols with magnesium iodide in acetonitrile produced the corresponding olefins in excellent isolated yields at room temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave it mixture of cis- and trans- alkenes. However, the cyclic sulfate of cyclic cis-diol afforded the corresponding cis-alkene only.",

author = "Jang, {Doo Ok} and Joo, {Yung Hyup}",

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T1 - A convenient method for the synthesis of alkenes from vic-diols via cyclic sulfates with magnesium iodide

AU - Jang, Doo Ok

AU - Joo, Yung Hyup

PY - 1998

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N2 - Reaction of cyclic sulfates of vic-diols with magnesium iodide in acetonitrile produced the corresponding olefins in excellent isolated yields at room temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave it mixture of cis- and trans- alkenes. However, the cyclic sulfate of cyclic cis-diol afforded the corresponding cis-alkene only.

AB - Reaction of cyclic sulfates of vic-diols with magnesium iodide in acetonitrile produced the corresponding olefins in excellent isolated yields at room temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave it mixture of cis- and trans- alkenes. However, the cyclic sulfate of cyclic cis-diol afforded the corresponding cis-alkene only.

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DO - 10.1080/00032719808006486

M3 - Article

AN - SCOPUS:0000780907

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JO - Synthetic Communications

JF - Synthetic Communications

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ER -

A convenient method for the synthesis of alkenes from vic-diols via cyclic sulfates with magnesium iodide

Abstract

All Science Journal Classification (ASJC) codes

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