A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas

Dae Woon Jeong; Won Jun Jang; Jae Oh Shim; Won Bi Han; Kyung Won Jeon; Yong Chil Seo; Hyun Seog Roh; Jae Hoi Gu; Yong Taek Lim

doi:10.1007/s10163-014-0272-8

A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas

Dae Woon Jeong, Won Jun Jang, Jae Oh Shim, Won Bi Han, Kyung Won Jeon, Yong Chil Seo, Hyun Seog Roh, Jae Hoi Gu, Yong Taek Lim

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO₂ at a very high gas hourly space velocity (GHSV) of 40,057 h⁻¹. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite.

Original language	English
Pages (from-to)	650-656
Number of pages	7
Journal	Journal of Material Cycles and Waste Management
Volume	16
Issue number	4
DOIs	https://doi.org/10.1007/s10163-014-0272-8
Publication status	Published - 2014 Oct

Bibliographical note

Funding Information:
Acknowledgments This work was supported by the New and Renewable Energy Technology Development Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) Grant funded by the Korea government Ministry of Knowledge Economy (2011T100200273). This work was supported (in part) by the Yonsei University Research Fund of 2013.

Publisher Copyright:
© 2014, Springer Japan.

All Science Journal Classification (ASJC) codes

Waste Management and Disposal
Mechanics of Materials

Access to Document

10.1007/s10163-014-0272-8

Cite this

Jeong, D. W., Jang, W. J., Shim, J. O., Han, W. B., Jeon, K. W., Seo, Y. C., Roh, H. S., Gu, J. H., & Lim, Y. T. (2014). A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas. Journal of Material Cycles and Waste Management, 16(4), 650-656. https://doi.org/10.1007/s10163-014-0272-8

@article{52a62caa2a8f462db6f364d1754b8e5c,

title = "A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas",

abstract = "A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h−1. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite.",

author = "Jeong, {Dae Woon} and Jang, {Won Jun} and Shim, {Jae Oh} and Han, {Won Bi} and Jeon, {Kyung Won} and Seo, {Yong Chil} and Roh, {Hyun Seog} and Gu, {Jae Hoi} and Lim, {Yong Taek}",

note = "Funding Information: Acknowledgments This work was supported by the New and Renewable Energy Technology Development Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) Grant funded by the Korea government Ministry of Knowledge Economy (2011T100200273). This work was supported (in part) by the Yonsei University Research Fund of 2013. Publisher Copyright: {\textcopyright} 2014, Springer Japan.",

year = "2014",

month = oct,

doi = "10.1007/s10163-014-0272-8",

language = "English",

volume = "16",

pages = "650--656",

journal = "Journal of Material Cycles and Waste Management",

issn = "1438-4957",

publisher = "Springer Japan",

number = "4",

}

TY - JOUR

T1 - A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas

AU - Jeong, Dae Woon

AU - Jang, Won Jun

AU - Shim, Jae Oh

AU - Han, Won Bi

AU - Jeon, Kyung Won

AU - Seo, Yong Chil

AU - Roh, Hyun Seog

AU - Gu, Jae Hoi

AU - Lim, Yong Taek

N1 - Funding Information: Acknowledgments This work was supported by the New and Renewable Energy Technology Development Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) Grant funded by the Korea government Ministry of Knowledge Economy (2011T100200273). This work was supported (in part) by the Yonsei University Research Fund of 2013. Publisher Copyright: © 2014, Springer Japan.

PY - 2014/10

Y1 - 2014/10

N2 - A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h−1. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite.

AB - A comparative study on Fe/Al, Fe/Al/Cu, and Fe/Al/Ni catalysts in high-temperature water–gas shift reaction (HT–WGS) using simulated waste-derived synthesis gas has been carried out. The metal oxide (Cu and Ni) and aluminum incorporated Fe catalysts were designed to get highly active HT–WGS catalysts. Despite the high CO concentration in the simulated waste-derived synthesis gas, Fe/Al/Cu catalyst exhibited the highest CO conversion (84 %) and 100 % selectivity to CO2 at a very high gas hourly space velocity (GHSV) of 40,057 h−1. The outstanding catalytic performance is mainly due to easier reducibility, the synergy effect of Cu and Al, and the stability of the magnetite.

UR - http://www.scopus.com/inward/record.url?scp=84916593600&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84916593600&partnerID=8YFLogxK

U2 - 10.1007/s10163-014-0272-8

DO - 10.1007/s10163-014-0272-8

M3 - Article

AN - SCOPUS:84916593600

SN - 1438-4957

VL - 16

SP - 650

EP - 656

JO - Journal of Material Cycles and Waste Management

JF - Journal of Material Cycles and Waste Management

IS - 4

ER -

A comparison study on high-temperature water–gas shift reaction over Fe/Al/Cu and Fe/Al/Ni catalysts using simulated waste-derived synthesis gas

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this