A belted monofacial ionophore featuring high selectivity for lithium ion complexation

Leo A. Paquette; Jinsung Tae; Eugene R. Hickey; Robin D. Rogers

doi:10.1002/(SICI)1521-3773(19990517)38:10<1409::AID-ANIE1409>3.0.CO;2-U

A belted monofacial ionophore featuring high selectivity for lithium ion complexation

Leo A. Paquette, Jinsung Tae, Eugene R. Hickey, Robin D. Rogers

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO₄.

Original language	English
Pages (from-to)	1409-1411
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	10
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990517)38:10<1409::AID-ANIE1409>3.0.CO;2-U
Publication status	Published - 1999 May 17

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/(SICI)1521-3773(19990517)38:10<1409::AID-ANIE1409>3.0.CO;2-U

Cite this

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abstract = "Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO4.",

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AU - Tae, Jinsung

AU - Hickey, Eugene R.

AU - Rogers, Robin D.

PY - 1999/5/17

Y1 - 1999/5/17

N2 - Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO4.

AB - Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO4.

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ER -

A belted monofacial ionophore featuring high selectivity for lithium ion complexation

Abstract

All Science Journal Classification (ASJC) codes

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