[60]Fullerene as a versatile four-electron donor ligand

Hyunjoon Song; Kwangyeol Lee; Moon Gun Choi; Joon T. Park

doi:10.1021/om020038f

[60]Fullerene as a versatile four-electron donor ligand

Hyunjoon Song, Kwangyeol Lee, Moon Gun Choi, Joon T. Park

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A new 1,2-σ-type C₆₀ compound, Os₃(CO)₇(CNR)(μ₃-CNR)(PPh₃)(μ ₃-η¹:η¹:η²-C₆₀) (2; R = CH₂Ph), is formed from Os₃(CO)₈(CNR)(μ₃-CNR)(μ₃-η ¹:η²:η¹-C₆₀) (1) upon substitution of CO with PPh₃ on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh₃ results in a π-type C₆₀ complex, Os₃(CO)₆(CNR)(μ₃-CNCH₂C₆H₄)(PPh₃)(μ-PPh₂)(μ-η²:η²-C₆₀) (3), with an Os-Os bond cleavage.

Original language	English
Pages (from-to)	1756-1758
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	9
DOIs	https://doi.org/10.1021/om020038f
Publication status	Published - 2002 Apr 29

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{83246ab66f27493ca8a38dbc015dc069,

title = "[60]Fullerene as a versatile four-electron donor ligand",

abstract = "A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.",

author = "Hyunjoon Song and Kwangyeol Lee and Choi, {Moon Gun} and Park, {Joon T.}",

year = "2002",

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doi = "10.1021/om020038f",

language = "English",

volume = "21",

pages = "1756--1758",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - [60]Fullerene as a versatile four-electron donor ligand

AU - Song, Hyunjoon

AU - Lee, Kwangyeol

AU - Choi, Moon Gun

AU - Park, Joon T.

PY - 2002/4/29

Y1 - 2002/4/29

N2 - A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.

AB - A new 1,2-σ-type C60 compound, Os3(CO)7(CNR)(μ3-CNR)(PPh3)(μ 3-η1:η1:η2-C60 ) (2; R = CH2Ph), is formed from Os3(CO)8(CNR)(μ3-CNR)(μ3-η 1:η2:η1-C60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a π-type C60 complex, Os3(CO)6(CNR)(μ3-CNCH2C6 H4)(PPh3)(μ-PPh2)(μ-η2 :η2-C60) (3), with an Os-Os bond cleavage.

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JO - Organometallics

JF - Organometallics

IS - 9

ER -

[60]Fullerene as a versatile four-electron donor ligand

Abstract

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