3D-Printed Graphene/Polylactic Acid Electrodes Promise High Sensitivity in Electroanalysis

C. Lorena Manzanares Palenzuela; Filip Novotný; Petr Krupička; Zdeněk Sofer; Martin Pumera

doi:10.1021/acs.analchem.8b00083

3D-Printed Graphene/Polylactic Acid Electrodes Promise High Sensitivity in Electroanalysis

C. Lorena Manzanares Palenzuela, Filip Novotný, Petr Krupička, Zdeněk Sofer, Martin Pumera

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

192 Citations (Scopus)

Abstract

Additive manufacturing provides a unique tool for prototyping structures toward electrochemical sensing, due to its ability to produce highly versatile, tailored-shaped devices in a low-cost and fast way with minimized waste. Here we present 3D-printed graphene electrodes for electrochemical sensing. Ring-and disc-shaped electrodes were 3D-printed with a Fused Deposition Modeling printer and characterized using cyclic voltammetry and scanning electron microscopy. Different redox probes K₃Fe(CN)₆:K₄Fe(CN)₆, FeCl₃, ascorbic acid, Ru(NH₃)₆Cl₃, and ferrocene monocarboxylic acid) were used to assess the electrochemical performance of these devices. Finally, the electrochemical detection of picric acid and ascorbic acid was carried out as proof-of-concept analytes for sensing applications. Such customizable platforms represent promising alternatives to conventional electrodes for a wide range of sensing applications.

Original language	English
Pages (from-to)	5753-5757
Number of pages	5
Journal	Analytical Chemistry
Volume	90
Issue number	9
DOIs	https://doi.org/10.1021/acs.analchem.8b00083
Publication status	Published - 2018 May 1

Bibliographical note

Funding Information:
This work was supported by the project Advanced Functional Nanorobots (Reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR). Z.S. was supported by Czech Science Foundation (GACR No. 16-05167S) and Neuron Foundation for Science support.

Publisher Copyright:
© 2018 American Chemical Society.

All Science Journal Classification (ASJC) codes

Analytical Chemistry

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10.1021/acs.analchem.8b00083

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abstract = "Additive manufacturing provides a unique tool for prototyping structures toward electrochemical sensing, due to its ability to produce highly versatile, tailored-shaped devices in a low-cost and fast way with minimized waste. Here we present 3D-printed graphene electrodes for electrochemical sensing. Ring-and disc-shaped electrodes were 3D-printed with a Fused Deposition Modeling printer and characterized using cyclic voltammetry and scanning electron microscopy. Different redox probes K3Fe(CN)6:K4Fe(CN)6, FeCl3, ascorbic acid, Ru(NH3)6Cl3, and ferrocene monocarboxylic acid) were used to assess the electrochemical performance of these devices. Finally, the electrochemical detection of picric acid and ascorbic acid was carried out as proof-of-concept analytes for sensing applications. Such customizable platforms represent promising alternatives to conventional electrodes for a wide range of sensing applications.",

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AU - Sofer, Zdeněk

AU - Pumera, Martin

N1 - Funding Information: This work was supported by the project Advanced Functional Nanorobots (Reg. No. CZ.02.1.01/0.0/0.0/15_003/0000444 financed by the EFRR). Z.S. was supported by Czech Science Foundation (GACR No. 16-05167S) and Neuron Foundation for Science support. Publisher Copyright: © 2018 American Chemical Society.

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3D-Printed Graphene/Polylactic Acid Electrodes Promise High Sensitivity in Electroanalysis

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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